铜钼在半导体中的作用有哪些

铜钼在半导体中的作用有哪些,第1张

铜钼在半导体中有可调的热膨胀系数,高导热率及其高强度的作用。钼熔点、沸点高,高温强度好,抗摩耐腐蚀,热传导率大,热膨胀系数小,淬透性好等优点,使它在宇航、兵器、电子、化工等领域广泛应用。钼的密度基本上接近于理论密度,因此其具有高强度,内部安排均匀和优秀的抗高温蠕变功能,被广泛使用于生产蓝宝石晶体生长炉内的反射屏。

编译 | 李言

Nature , 17 March 2022, Volume 603 Issue 7901

《自然》 2022年3月17日,第603卷,7901期

化学 Chemistry

High-resolution laser resonances of antiprotonic helium in superfluid 4He

超流体4He中反质子氦的高分辨率激光共振

作者:Anna Sótér, Hossein Aghai-Khozani et al.

链接:

https://www.nature.com/articles/s41586-022-04440-7

摘要

在此,我们展示了当一个具有反质子成分的奇异氦原子被嵌入到超流氦中时,它的可见波长谱线保持了亚千兆赫的线宽。当原子周围的液体转变为超流相时,反质子激光共振线宽突然减小。

这就解决了电子和反质子之间自旋-自旋相互作用所产生的超精细结构,相对光谱分辨率为106的两部分,尽管反质子氦位于正常物质原子的密集矩阵中。在激光激发期间,反质子原子的电子壳层保持一个大约40皮米的小半径。

这意味着,其他含有反核的氦原子以及带负电荷的介子和超子,包括在超流氦中形成的奇异夸克,可以通过具有高光谱分辨率的激光光谱学来研究,从而能够确定粒子的质量。清晰的光谱线可以探测到宇宙射线的反质子,也可以搜索到滞留在液氦目标中的反氘核。

Abstract

Here we show that when an exotic helium atom with a constituent antiproton is embedded into superfluid helium, its visible-wavelength spectral line retains a sub-gigahertz linewidth. An abrupt reduction in the linewidth of the antiprotonic laser resonance was observed when the liquid surrounding the atom transitioned into the superfluid phase. This resolved the hyperfine structure arising from the spin–spin interaction between the electron and antiproton with a relative spectral resolution of two parts in 106, even though the antiprotonic helium resided in a dense matrix of normal matter atoms. The electron shell of the antiprotonic atom retains a small radius of approximately 40 picometres during the laser excitation. This implies that other helium atoms containing antinuclei, as well as negatively charged mesons and hyperons that include strange quarks formed in superfluid helium, may be studied by laser spectroscopy with a high spectral resolution, enabling the determination of the particle masses. The sharp spectral lines may enable the detection of cosmic-ray antiprotons or searches for antideuterons that come to rest in liquid helium targets.

Flat-surface-assisted and self-regulated oxidation resistance of Cu(111)

平坦表面和自调节抗氧化性能的铜薄膜材料Cu(111)

作者:Su Jae Kim, Yong In Kim, Bipin Lamichhane et al.

链接:

https://www.nature.com/articles/s41586-021-04375-5#Sec9

摘要

氧化会降低铜的性能,而铜的性能对其使用至关重要,尤其是在半导体工业和电光应用中。在此,我们展示半永久抗氧化的铜薄膜制备,因为它们由平坦的表面组成,只有偶发单原子台阶。第一性原理计算证实,单原子台阶边缘与平坦表面一样不受氧的影响,并且一旦达到50%氧面心立方FCC表面位置覆盖率,氧原子表面吸附就被抑制。这些综合效应解释了超平摊铜表面特殊的抗氧化性。

Abstract

Oxidation can deteriorate the properties of copper that are critical for its use, particularly in the semiconductor industry and electro-optics applications. Here we report the fabrication of copper thin films that are semi-permanently oxidation resistant because they consist of flat surfaces with only occasional mono-atomic steps. First-principles calculations confirm that mono-atomic step edges are as impervious to oxygen as flat surfaces and that surface adsorption of O atoms is suppressed once an oxygen face-centred cubic (fcc) surface site coverage of 50% has been reached. These combined effects explain the exceptional oxidation resistance of ultraflat Cu surfaces.

物理学 Physics

Unbiasing fermionic quantum Monte Carlo with a quantum computer

无偏的费米子量子蒙特卡罗与量子计算机

作者:William J. Huggins, Bryan A. O’Gorman, Nicholas C. Rubin, David R. Reichman, Ryan Babbush &Joonho Lee

链接:

https://www.nature.com/articles/s41586-021-04351-z

摘要

用约束来控制费米符号问题保证了量子蒙特卡罗计算(QMC)的效率,但代价是由于经典计算的灵活性有限而可能存在显著的偏差。

在此,我们提出了一种将QMC与量子计算相结合的方法来减少这种偏差。我们的方案在实验中实现了,我们使用了多达16个量子位来进行无偏约束QMC计算,这些计算是在多达120个轨道的化学系统上进行的。

这些实验代表了在量子计算机的帮助下进行的最大的化学模拟,同时实现了与最先进的经典方法竞争的精度,而不需要负担的错误缓解。

与流行的变分量子本征求解器相比,我们的量子-经典混合计算模型为电子结构问题提供了另一种实现实际量子优势的途径,而不需要非常精确的基态波函数的制备和测量。

Abstract

Controlling the fermionic sign problem with constraints ensures the efficiency of QMC at the expense of potentially significant biases owing to the limited flexibility of classical computation. Here we propose an approach that combines constrained QMC with quantum computation to reduce such biases. We implement our scheme experimentally using up to 16 qubits to unbias constrained QMC calculations performed on chemical systems with as many as 120 orbitals. These experiments represent the largest chemistry simulations performed with the help of quantum computers, while achieving accuracy that is competitive with state-of-the-art classical methods without burdensome error mitigation. Compared with the popular variational quantum eigensolver, our hybrid quantum-classical computational model offers an alternative path towards achieving a practical quantum advantage for the electronic structure problem without demanding exceedingly accurate preparation and measurement of the ground-state wavefunction.

HighlWind dispersal of battery-free wireless devices

风扩散的无电池无线设备

作者:Vikram Iyer, Hans Gaensbauer, Thomas L. Daniel &Shyamnath Gollakota

链接:

https://www.nature.com/articles/s41586-021-04363-9

摘要

植物覆盖了地球陆地的很大一部分,尽管大多数物种都不能运动。为了运输繁殖后代,许多植物进化出了利用风传播种子的机制。

例如,蒲公英的种子有一种刚毛状的丝状结构,可以降低其末端速度,并在种子飘向地面时帮助其定位。受此启发,我们在此展示无电池无线的风扩散传感设备。我们的毫米级设备重量为30毫克,基于一个灵活的基板上,使用可编程的、现成的部件,为各种传感和计算应用提供可扩展性和灵活性。

该系统使用轻型太阳能电池和能量收集电路供电,电路对低光照和可变光照条件非常稳定,并有一个反向散射通信链路,可以实现数据传输。

为了实现太阳能收集所必需的大面积分散和垂直降落,我们开发了蒲公英启发的薄膜多孔结构,其终端速度为0.87 0.02米/秒,空气动力学稳定性,垂直降落的概率超过95%。户外环境实验的结果表明,这些设备可以在轻柔到正常的微风中移动50-100米。

最后,在自然系统中,个别种子形态的差异导致一些种子落得更近,而另一些则传播得更远。我们采用了类似的方法,并展示了我们如何调节结构的孔隙度和直径,以实现设备间的分散变化。

Abstract

Plants cover a large fraction of the Earth’s land mass despite most species having limited to no mobility. To transport their propagules, many plants have evolved mechanisms to disperse their seeds using the wind. A dandelion seed, for example, has a bristly filament structure that decreases its terminal velocity and helps orient the seed as it wafts to the ground. Inspired by this, we demonstrate wind dispersal of battery-free wireless sensing devices. Our millimetre-scale devices weigh 30 milligrams and are designed on a flexible substrate using programmable, off-the-shelf parts to enable scalability and flexibility for various sensing and computing applications. The system is powered using lightweight solar cells and an energy harvesting circuit that is robust to low and variable light conditions, and has a backscatter communication link that enables data transmission. To achieve the wide-area dispersal and upright landing that is necessary for solar power harvesting, we developed dandelion-inspired, thin-film porous structures that achieve a terminal velocity of 0.87  0.02 metres per second and aerodynamic stability with a probability of upright landing of over 95%. Our results in outdoor environments demonstrate that these devices can travel 50–100 metres in gentle to moderate breeze. Finally, in natural systems, variance in inpidual seed morphology causes some seeds to fall closer and others to travel farther. We adopt a similar approach and show how we can modulate the porosity and diameter of the structures to achieve dispersal variation across devices.

地球科学 Geoscience

Limited increases in savanna carbon stocks over decades of fire suppression

几十年没有火灾的稀树草原碳储量的增长有限

作者:Yong Zhou, Jenia Singh, John R. Butnor, Corli Coetsee, Peter B. Boucher, Madelon F. Case, Evan G. Hockridge, Andrew B. Davies &A. Carla Staver

链接:

https://www.nature.com/articles/s41586-022-04438-1

摘要

在此,我们提供了一个首次直接评估一个60年没有火灾的非洲湿地大草原整个生态系统碳响应

我们发现灭火增加整个生态系统碳储存只有35.4 12%(平均值 标准错误),即使树木覆盖增加了78.9 29.3%,相应的总收益为23.0 6.1 Mg C ha 1 平均约为0.35 0.09 Mg C ha 1 year 1 ,低于之前的设想。

经常被烧毁的稀树草原地下有大量的碳,特别是在生物量和深层土壤中。这些地下水库在造林或灭火计划中没有得到充分考虑,但这可能意味着热带稀树草原的十年封存潜力是微不足道的,特别是与随之而来的生物多样性和功能损失相比。

Abstract

Here we provide one of the first direct estimates of whole-ecosystem carbon response to more than 60 years of fire exclusion in a mesic African savanna. We found that fire suppression increased whole-ecosystem carbon storage by only 35.4   12% (mean   standard error), even though tree cover increased by 78.9   29.3%, corresponding to total gains of 23.0   6.1 Mg C ha 1 at an average of about 0.35   0.09 Mg C ha 1  year 1 , more than an order of magnitude lower than previously assumed. Frequently burned savannas had substantial belowground carbon, especially in biomass and deep soils. These belowground reservoirs are not fully considered in afforestation or fire-suppression schemes but may mean that the decadal sequestration potential of savannas is negligible, especially weighed against concomitant losses of biopersity and function.

化学 Chemistry

New land-use-change emissions indicate a declining CO2 airborne fraction

新的土地利用变化排放表明空气中二氧化碳的比例在下降

作者:Margreet J. E. van Marle, Dave van Wees, Richard A. Houghton, Robert D. Field, Jan Verbesselt &Guido. R. van der Werf

链接:

https://www.nature.com/articles/s41586-021-04376-4

摘要

在此,我们使用可见性数据在关键的森林砍伐区构建了一个土地利用与土地覆盖变化(LULCC)排放数据集。这些可见性观测与火灾排放相关,而火灾排放又与LULCC相关。虽然这是间接的,但它提供了一个长期一致的LULCC排放数据集,表明自1958年开始CO2浓度测量以来,热带森林砍伐排放大幅增加。

到目前为止,这些排放被认为是相对稳定的,导致空气中的比例不断增加。然而,我们的结果表明,自1959年以来,大气中CO2含量下降了0.014 0.010 decade 1。这表明,陆地-海洋联合汇的增长速度至少与人为排放的增长速度一样快。

Abstract

Here we construct a LULCC emissions dataset using visibility data in key deforestation zones. These visibility observations are a proxy for fire emissions, which are — in turn — related to LULCC. Although indirect, this provides a long-term consistent dataset of LULCC emissions, showing that tropical deforestation emissions increased substantially (0.16 Pg C decade 1) since the start of CO2 concentration measurements in 1958. So far, these emissions were thought to be relatively stable, leading to an increasing airborne fraction. Our results, however, indicate that the CO2 airborne fraction has decreased by 0.014   0.010 decade 1 since 1959. This suggests that the combined land–ocean sink has been able to grow at least as fast as anthropogenic emissions.

古代主要用于器皿、艺术品及武器铸造,比较有名的器皿及艺术品如司母戊鼎、四羊方尊。

现代被广泛地应用于电气、轻工、机械制造、建筑工业、国防工业等领域。具体如下:

1、用于电器和电子市场

使用寿命比较长的电器:电线、母线、变压器绕组、重型马达、电话线和电话电缆铜

使用寿命比较短的电器:比如:小型电器和消费电子产品

2、交通设备

自动散热器是这方面最重要的终端用户,然而,铜在自动电器和电子产品中的使用飞速增长,而在热交换器市场中的使用则有所下降。小轿车的平均使用寿命是10-15年,几乎所有的铜都是在它的整体拆卸和回收前来进行回收的。

3、工业机器和设备

硬币和军火是这方面主要的终端用户。子d很少回收,一些硬币可以熔化,而还有许多则由收藏者或储蓄者保存,不可以进行回收。在机械和运输车辆制造中,用于制造工业阀门和配件、仪表、滑动轴承、模具、热交换器和泵等。

在化学工业中广泛应用于制造真空器、蒸馏锅、酿造锅等。

在国防工业中用以制造子d、炮d、q炮零件等,每生产300万发子d,需用铜13~14吨。

在建筑工业中,用做各种管道、管道配件、装饰器件等。

4、医学

20世纪70年代,中国医学发明家刘同庆 研究发现,铜元素具有极强的抗癌功能,并成功研制出相应的抗癌药物“克癌症7851”,在临床上获得成功。后来,墨西哥科学家也发现铜有抗癌功能。新世纪,英国研究人员又发现,铜元素有很强的杀菌作用。相信不久的将来,铜元素将为提高人类健康水平做出巨大贡献。

5、有机化学

有机化学中,有机铜锂化合物是一类重要的金属有机化合物。

6、合金:铜可用于制造多种合金。

(1)黄铜

黄铜是铜与锌的合金,因色黄而得名。黄铜的机械性能和耐磨性能都很好,可用于制造精密仪器、船舶的零件、q炮的d壳等。黄铜敲起来声音好听,因此锣、钹、铃、号等乐器都是用黄铜制做的。

(2)航海黄铜

铜与锌、锡的合金,抗海水侵蚀,可用来制作船的零件、平衡器。

(3)青铜

铜与锡的合金叫青铜,因色青而得名。青铜一般具有较好的耐腐蚀性、耐磨性、铸造性和优良的机械性能。用于制造精密轴承、高压轴承、船舶上抗海水腐蚀的机械零件以及各种板材、管材、棒材等。青铜还有一个反常的特性——“热缩冷胀”,用来铸造塑像,冷却后膨胀,可以使眉目更清楚。

(4)磷青铜

铜与锡、磷的合金,坚硬,可制d簧。

(5)白铜

白铜是铜与镍的合金,其色泽和银一样,银光闪闪,不易生銹。常用于制造硬币、电器、仪表和装饰品。

(6)十八开金(18K金或称玫瑰金)

6/24的铜与18/24的金的合金。红黄色,硬度大,可用来制作首饰、装饰品。

扩展资料

铜与木的结合:

铜木缘应运而生,产品采用铜材与木材的巧妙搭配,材料与众不同,风格独具匠心。铜,材质高贵,器物典雅;木,原汁原味,极具观赏和收藏价值。铜+木,不是简单的堆砌,而是融艺术、观赏、收藏、实用价值为一体,汲取传统文化之精华,以匠心精神,打造经典绝伦的灯饰产品。

随着时代的变迁,消费呈现出年轻化趋势,品牌需要引领潮流、顺势而上,才能有所作为。传统中式灯虽然典雅,但是古朴,缺乏灵气;现代灯虽然前卫,但是略显轻浮而缺乏内涵。

铜木缘肩负着“现代铜木家居探索者”的重大使命,集灯具、家具、饰品为一体,将现代美与古典美深度融合,使之成为不可分割的整体,浑然天成,不事雕饰,营造出素雅、时尚、简约的家居环境,深得消费年轻消费群体的追捧,大大填补现代铜木家居市场的空白。

由于铜具有上述优良性能,所以在工业上有着广泛的用途。包括电气行业、机械制造、交通、建筑等方面。目前,铜在电气和电子行业这一领域中主要用于制造电线、通讯电缆和其他成品如电动机、发电机转子及电子仪器、仪表等,这部分用量约占工业总需求量的一半左右。

铜及铜合金在计算机芯片、集成电路、晶体管、印刷电路版等器材器件中都占有重要地位。例如,晶体管引线用高导电、高导热的铬锆铜合金。最近,国际知名计算机公司IBM已采用铜代替硅芯片中的铝,这标志着人类最古老的金属在半导体技术应用方面的最新突破。 

参考资料百度百科-铜


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